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A variety of isomers are known, but they all feature an amyl group attached to the nitrite functional group. The alkyl group is unreactive and the chemical and biological properties are mainly due to the nitrite group. Like other alkyl nitritesamyl nitrite is bioactive in mammals, being a vasodilatorwhich is the basis of its use as a prescription medicine. As an inhalant, it also has a psychoactive effect, which has led to its recreational use with its smell being described Elite modeling agency Pickering that of old socks or dirty feet.

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